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      鈣鈦礦材料 DPP-DTT

      簡要描述:Luminosyn™ DPP-DTT (also referred to as PDPP2T-TT-OD) is now available featuring

      • 產品型號:
      • 廠商性質:生產廠家
      • 更新時間:2025-05-07
      • 訪  問  量:3341

      詳細介紹

      Luminosyn™ DPP-DTT (also referred to as PDPP2T-TT-OD) is now available featuring:

       

      High molecular weight - higher molecular weight offers higher charge mobility

      High purity - DPP-DTT is purified via Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere

      Batch-specific GPC data - so you have confidence in what you are ordering. Also, GPC data is always convenient for your thesis and publications

      Large quantity orders - so you can plan your experiments with polymer from the same batch

       

      價格

      Batch

      Quantity

      Price

      M315

      100 mg

      4800.45

      M315

      250 mg

      8011.45

      M315

      500 mg

      12635.29

      M315

      1g

      20871.50

      M315

      2g

      36926.50

      *for 5 - 10 grams order quantity, the lead time is 4-6 weeks.

       

      Batch Details

      Batch

      Mw

      Mn

      PDI

      M314

      292,200

      74,900

      3.90

      M315

      278,781

      76,323

      3.65

       

      General Information

      Synonyms

      PDBT-co-DTT

      PTT-DTDPP

      PDPP-DTT

      DPPT-TT

      DPP-TTT

      PDPP2T-TT

      PDPP2T-TT-OD

      DPPDTT

      Poly[2,5-(2-octyldodecyl)-3,6-diketopyrrolopyrrole-alt-5,5-(2,5-di(thien-2-yl)thieno [3,2-b]thiophene)]

      CAS number

      1260685-66-2 (1444870-74-9)

      Chemical formula

      (C60H88N2O2S4)n

      HOMO/LUMO

      HOMO = -5.2 eV, LUMO = -3.5 eV [2]

      Solubility

      Chloroform, chlorobenzene and dichlorobenzene

      Classification/Family

      Bithiophene, Thienothiophene, Organic semiconducting materials, Low band-gap polymers, Organic photovoltaics, Polymer solar cells, OFETs

       

      Chemical structure and product image of DPP-DTT, CAS No. 260685-66-2.

       

      OFET and Sensing Applications
      The exceptional high mobility of this polymer of up to 10 cm2/Vs [2] via solution-processed techniques, combined with its intrinsic air stability (even during annealing) has made PDPP2T-TT-OD of significant interest for OFET and sensing purposes.

      While the highest mobilities require exceptional molecular weights of around 500 kD (and with commensurate solubility issues), high mobilities in the region of 1-3 cm2/Vs can still be achieved with good solution-processing at around 250 kD. As such, we have made a range of molecular weights available to allow for different processing techniques.

      In our own tests, we have found that by using simple spin-coating onto an OTS-treated silicon substrate (using our prefabricated test chips), high mobilities comparable to the literature can be achieved  (1-3 cm2/Vs). Further improvements may also be possible with more advanced strain-inducing deposition techniques.

      Example OFET characteristics for DPP-DTT (M313) solution processed from chlorobenzene on a 300 nm SiO2 substrate treated with OTS. Output characteristic (top left), transfer curves (top right), mobility fitting (bottom left) and calculated mobility (bottom right).

       

      Photovoltaic Applications
      Although shown as a promising hole-mobility polymer for OFETs, when used as the donor material in a bulk heterojunction photovoltaic (with PC70BM as the acceptor), initial efficiencies of 1.6% were achieved for DPP-DTT [3]. The low device metrics were attributed to poor film morphology. However, a higher efficiency of 6.9% was achieved by using thicker film (220 nm) [4].

      PDPP2T-TT-OD has also recently been used successfully as an active-layer dopant material in PTB7-based devices [5]. An improvement in device performance was observed, with average efficiencies increasing from 7.6% to 8.3% when the dopant concentration of DPP-DTT was 1 wt%. The use of DPP-DTT as a high-mobility hole-interface layer for perovskite hybrid devices has also been investigated [6].

      Synthetic route
      DPP-DTT synthesis: DPP-DTT was synthesised by following the procedures described in [2] and [3] (please refer to the following references):

      With 2-thiophenecarbonitrile and dimethyl succinate as starting materials in t-amyl alcohol, it gave 3,6-Dithiophen-2-yl-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione. Alkylation of 3,6-Dithiophen-2-yl-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione with 2-octyldodecylbromide in dimethylformamide afforded 3,6-bis(thiophen-2-yl)-2,5-bis(2-octyldodecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione. Further bromination gave 3,6-bis(5-bromothiophen-2-yl)-2,5-bis(2-octyldodecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione (M1).

      Further reaction of M1 with 2,5-bis(trimethylstannyl)thieno[3,2-b]thiophene (M2) under Stille coupling conditions gave the target polymer DPP-DTT, which was further purified via Soxhlet extraction with methanol, hexane and then chloroform.

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      上海巨納科技有限公司 公司地址:上海市虹口區寶山路778號海倫國際大廈5樓   技術支持:化工儀器網
      • 聯系人:袁文軍
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